Useful synthetic reagents derived from 1-triisopropylsilylpropyne and 1,3bis-[triisopropylsilyl]propyne, direct, stereoselective synthesis of either Z or E enynes

Elias James Corey; Christoph Rücker

doi:10.1016/S0040-4039(00)86930-0

Useful synthetic reagents derived from 1-triisopropylsilylpropyne and 1,3bis-[triisopropylsilyl]propyne, direct, stereoselective synthesis of either Z or E enynes

Elias James Corey
, Christoph Rücker

Harvard Universität

Publikation: Beiträge in Zeitschriften › Zeitschriftenaufsätze › Forschung › Begutachtung

146 Zitate (Scopus)

Abstract

Lithio reagents derived from 1-triisopropylsilylpropyne (1) and 1,3-bis-[triisopropylsilyl]propane (3) are effective for the synthesis of Z or E terminal enyne units (CHCHCCH) and for carboncarbon bond formation with halides, aldehydes, ketones, epoxides, and α,β-enones.

Originalsprache	Englisch
Zeitschrift	Tetrahedron Letters
Jahrgang	23
Ausgabenummer	7
Seiten (von - bis)	719-722
Seitenumfang	4
DOIs	https://doi.org/10.1016/S0040-4039(00)86930-0
Publikationsstatus	Erschienen - 1982
Extern publiziert	Ja

Bibliographische Notiz

Funding Information:
cyclohexyl . The erythro stereochemistry of the adduct 8 was supported by (1) the pmr spectrum

Fachgebiete und Schlagwörter

Chemie

ASJC Scopus Sachgebiete

Organische Chemie
Wirkstoffforschung
Biochemie

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10.1016/S0040-4039(00)86930-0

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title = "Useful synthetic reagents derived from 1-triisopropylsilylpropyne and 1,3bis-[triisopropylsilyl]propyne, direct, stereoselective synthesis of either Z or E enynes",

abstract = "Lithio reagents derived from 1-triisopropylsilylpropyne (1) and 1,3-bis-[triisopropylsilyl]propane (3) are effective for the synthesis of Z or E terminal enyne units (CHCHCCH) and for carboncarbon bond formation with halides, aldehydes, ketones, epoxides, and α,β-enones.",

keywords = "Chemistry",

author = "Corey, \{Elias James\} and Christoph R{\"u}cker",

note = "Funding Information: cyclohexyl . The erythro stereochemistry of the adduct 8 was supported by (1) the pmr spectrum",

year = "1982",

doi = "10.1016/S0040-4039(00)86930-0",

language = "English",

volume = "23",

pages = "719--722",

journal = "Tetrahedron Letters",

issn = "1873-3581",

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number = "7",

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T1 - Useful synthetic reagents derived from 1-triisopropylsilylpropyne and 1,3bis-[triisopropylsilyl]propyne, direct, stereoselective synthesis of either Z or E enynes

AU - Corey, Elias James

AU - Rücker, Christoph

N1 - Funding Information: cyclohexyl . The erythro stereochemistry of the adduct 8 was supported by (1) the pmr spectrum

PY - 1982

Y1 - 1982

N2 - Lithio reagents derived from 1-triisopropylsilylpropyne (1) and 1,3-bis-[triisopropylsilyl]propane (3) are effective for the synthesis of Z or E terminal enyne units (CHCHCCH) and for carboncarbon bond formation with halides, aldehydes, ketones, epoxides, and α,β-enones.

AB - Lithio reagents derived from 1-triisopropylsilylpropyne (1) and 1,3-bis-[triisopropylsilyl]propane (3) are effective for the synthesis of Z or E terminal enyne units (CHCHCCH) and for carboncarbon bond formation with halides, aldehydes, ketones, epoxides, and α,β-enones.

KW - Chemistry

UR - https://www.scopus.com/pages/publications/0000997935

U2 - 10.1016/S0040-4039(00)86930-0

DO - 10.1016/S0040-4039(00)86930-0

M3 - Journal articles

SN - 1873-3581

VL - 23

SP - 719

EP - 722

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 7

ER -

Useful synthetic reagents derived from 1-triisopropylsilylpropyne and 1,3bis-[triisopropylsilyl]propyne, direct, stereoselective synthesis of either Z or E enynes

Abstract

Bibliographische Notiz

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