The 1,3 O→C silyl rearrangement of silyl enol ether anions - synthesis of α-silyl ketones.

E.J. Corey; Christoph Rücker

doi:10.1016/S0040-4039(01)81434-9

The 1,3 O→C silyl rearrangement of silyl enol ether anions - synthesis of α-silyl ketones.

E.J. Corey
, Christoph Rücker

Publikation: Beiträge in Zeitschriften › Zeitschriftenaufsätze › Forschung › Begutachtung

49 Zitate (Scopus)

Abstract

Silyl enol ethers with sterically hindered silyl groups are transformed into the corresponding α-silyl ketones by treatment with n-butyllithium/potassium tert-butylate.

Originalsprache	Englisch
Zeitschrift	Tetrahedron Letters
Jahrgang	25
Ausgabenummer	39
Seiten (von - bis)	4345-4348
Seitenumfang	4
DOIs	https://doi.org/10.1016/S0040-4039(01)81434-9
Publikationsstatus	Erschienen - 1984
Extern publiziert	Ja

Fachgebiete und Schlagwörter

Chemie

ASJC Scopus Sachgebiete

Organische Chemie
Wirkstoffforschung
Biochemie

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10.1016/S0040-4039(01)81434-9

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title = "The 1,3 O→C silyl rearrangement of silyl enol ether anions - synthesis of α-silyl ketones.",

abstract = "Silyl enol ethers with sterically hindered silyl groups are transformed into the corresponding α-silyl ketones by treatment with n-butyllithium/potassium tert-butylate.",

keywords = "Chemistry",

author = "E.J. Corey and Christoph R{\"u}cker",

year = "1984",

doi = "10.1016/S0040-4039(01)81434-9",

language = "English",

volume = "25",

pages = "4345--4348",

journal = "Tetrahedron Letters",

issn = "1873-3581",

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T1 - The 1,3 O→C silyl rearrangement of silyl enol ether anions - synthesis of α-silyl ketones.

AU - Corey, E.J.

AU - Rücker, Christoph

PY - 1984

Y1 - 1984

N2 - Silyl enol ethers with sterically hindered silyl groups are transformed into the corresponding α-silyl ketones by treatment with n-butyllithium/potassium tert-butylate.

AB - Silyl enol ethers with sterically hindered silyl groups are transformed into the corresponding α-silyl ketones by treatment with n-butyllithium/potassium tert-butylate.

KW - Chemistry

U2 - 10.1016/S0040-4039(01)81434-9

DO - 10.1016/S0040-4039(01)81434-9

M3 - Journal articles

SN - 1873-3581

VL - 25

SP - 4345

EP - 4348

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 39

ER -

The 1,3 O→C silyl rearrangement of silyl enol ether anions - synthesis of α-silyl ketones.

Abstract

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